Fluorine nitrate

Fluorine nitrate
Structural formulas of fluorine nitrate, showing its resonance structure
Ball-and-stick model of the fluorine nitrate molecule
Identifiers
3D model (JSmol)
Properties
FNO3
Molar mass 81.00 g·mol−1
Density 2.217 g/L[1]
Melting point −175 °C (−283.0 °F; 98.1 K)
Boiling point −46 °C (−51 °F; 227 K)
Thermochemistry
+10.46kJ/mol
Hazards
Main hazards Explosive gas
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Fluorine nitrate is an unstable derivative of nitric acid with the formula FNO
3. It is shock-sensitive.[1] Due to its instability, it is often produced from chlorine nitrate as needed.

References

  1. 1 2 Ruff, Otto; Kwansik, Walter (1935). "The fluorination of nitric acid. The nitroxyfluoride, NO3F". Angewandte Chemie. 48: 238–240. doi:10.1002/ange.19350481604.
  • Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9.
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO
3)−
4		 C NO−
3,
NH4NO3		 O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2		 Co(NO3)2,
Co(NO3)3		 Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2		 Tl(NO3)3,
TlNO3		 Pb(NO3)2 Bi(NO3)3
BiO(NO3)		 Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4		 Pr Nd Pm Sm Eu(NO3)3 Gd(NO3)3 Tb Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr
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