Indium(III) fluoride

Indium(III) fluoride
Names
IUPAC name
Indium(III) fluoride
Other names
Indium trifluoride
Identifiers
ECHA InfoCard 100.029.095
EC Number 232-005-0
Properties
InF3
Molar mass 171.82 g/mol
Melting point 1,172 °C (2,142 °F; 1,445 K)[1]
Structure
Rhombohedral, hR24
R-3c, No. 167
Hazards
Irritant (Xi)
R-phrases (outdated) R31, R36/37/38
S-phrases (outdated) S26, S36[2]
Flash point non-flammable
Related compounds
Other anions
Indium(III) chloride
Indium(III) bromide
Indium(III) iodide
Other cations
Aluminum fluoride
Gallium(III) fluoride
Thallium(I) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Indium(III) fluoride or indium trifluoride is the chemical compound composed of indium and fluorine with the formula InF3. It has a rhombohedral crystal structure identical to that of rhodium(III) fluoride .[3] It is formed by the reaction of indium(III) oxide with hydrogen fluoride or hydrofluoric acid.

Indium(III) fluoride is used in the synthesis of non-oxide glasses. It is also used as a catalyst for the addition of trimethylsilyl cyanide (TMSCN) to aldehydes to form cyanohydrins.[2]

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, p. 112, ISBN 0-8493-0594-2, retrieved 2008-06-19
  2. 1 2 "435848 Indium(III) fluoride 99.9+ % trace metals basis". Sigma-Aldrich. Retrieved 2008-06-19.
  3. Fergusen, G.; Trotter, J. (1987), Structure Reports for 1984, Part A, Springer, p. 122, ISBN 90-277-2470-9, retrieved 2008-06-19


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