Titanium(III) fluoride

Titanium(III) fluoride
Names
	IUPAC name Titanium(III) fluoride
	Other names Titanium trifluoride ; Titanous fluoride ; Trifluorotitanium
Identifiers
CAS Number	13470-08-1 ;
3D model (JSmol)	Interactive image;
ChemSpider	75341 ;
ECHA InfoCard	100.033.379
EC Number	236-732-4;
PubChem CID	83506;
CompTox Dashboard (EPA)	DTXSID9065495 ;
	InChI InChI=1S/3FH.Ti/h31H;/q;;;+3/p-3 Key: NLPMQGKZYAYAFE-UHFFFAOYSA-K ; InChI=1/3FH.Ti/h31H;/q;;;+3/p-3 Key: NLPMQGKZYAYAFE-DFZHHIFOAU;
	SMILES F[Ti](F)F;
Properties
Chemical formula	TiF3
Molar mass	104.862 g/mol
Appearance	violet to purple-red powder
Density	3.4 g/cm3
Melting point	1,200 °C (2,190 °F; 1,470 K)
Boiling point	1,400 °C (2,550 °F; 1,670 K)
Solubility in water	soluble
Magnetic susceptibility (χ)	+1300·10−6 cm3/mol
Structure
Crystal structure	Rhombohedral, hR24
Space group	R-3c, No. 167
Hazards[1]
Main hazards	Corrosive
GHS pictograms
GHS Signal word	Danger
GHS hazard statements	H314
GHS precautionary statements	P280, P305+351+338, P310
Related compounds
Other anions	Titanium(III) bromide ; Titanium(III) chloride ; Titanium(III) iodide
Related compounds	Titanium(IV) fluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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	Infobox references

Titanium(III) fluoride (Ti F₃) is an inorganic compound with the formula TiF₃. It is a violet solid. It adopts a perovskite-like structure such that each Ti center has octahedral coordination geometry and each fluoride ligand is doubly bridging.[2]

References

"Titanium(III) Fluoride". American Elements. Retrieved July 23, 2019.
H. Sowa; H. Ahsbahs (1998). "Pressure-Induced Octahedron Strain in VF₃-Type Compounds". Acta Crystallogr. B54: 578–584. doi:10.1107/S0108768198001207.

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[1] "Titanium(III) Fluoride". American Elements. Retrieved July 23, 2019.

[2] H. Sowa; H. Ahsbahs (1998). "Pressure-Induced Octahedron Strain in VF₃-Type Compounds". Acta Crystallogr. B54: 578–584. doi:10.1107/S0108768198001207.