Dihydrosirohydrochlorin

Dihydrosirohydrochlorin
Names
	Other names precorrin 2
Identifiers
CAS Number	82542-92-5 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:50602;
ChemSpider	26333172;
KEGG	C02463;
MeSH	15,23-dihydrosirohydrochlorin
PubChem CID	5280516;
	InChI InChI=1S/C42H48N4O16/c1-41(17-39(59)60)23(5-9-35(51)52)29-14-27-21(11-37(55)56)19(3-7-33(47)48)25(43-27)13-26-20(4-8-34(49)50)22(12-38(57)58)28(44-26)15-31-42(2,18-40(61)62)24(6-10-36(53)54)30(46-31)16-32(41)45-29/h14-16,23-24,43-44,46H,3-13,17-18H2,1-2H3,(H,47,48)(H,49,50)(H,51,52)(H,53,54)(H,55,56)(H,57,58)(H,59,60)(H,61,62)/b29-14-,30-16-,31-15-/t23-,24-,41+,42+/m1/s1 Key: CSWLXNNNLVVXKD-ZIBVGKFXSA-N;
	SMILES CC1(C(C2=CC3=NC(=CC4=C(C(=C(N4)CC5=C(C(=C(N5)C=C1N2)CC(=O)O)CCC(=O)O)CCC(=O)O)CC(=O)O)C(C3(C)CC(=O)O)CCC(=O)O)CCC(=O)O)CC(=O)O;
Properties
Chemical formula	C42H48N4O16
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Dihydrosirohydrochlorin is a macrocyclic metabolic intermediate in the biosynthesis of corrin, precursor to the tetrapyrrole pigment and cofactor F430. In terms of its biosynthesis, it is produced by dimethylation is uroporphyrinogen III, the progenitor of all natural tetrapyrroles.^[1] Dehydrogenation, i.e., removal of H₂, of dihydrosirohydrochlorin gives sirohydrochlorin.

References

↑ Mucha, Helmut; Keller, Eberhard; Weber, Hans; Lingens, Franz; Trösch, Walter (1985-10-07). "Sirohydrochlorin, a precursor of factor F430 biosynthesis in Methanobacterium thermoautotrophicum". FEBS Letters. 190 (1): 169–171. doi:10.1016/0014-5793(85)80451-8.

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