Lithium azide
Names | |
---|---|
IUPAC name
lithium azide | |
Identifiers | |
3D model (JSmol) |
|
ChemSpider | |
ECHA InfoCard | 100.039.237 |
PubChem CID |
|
| |
| |
Properties | |
LiN3 | |
Molar mass | 48.96 g·mol−1 |
Melting point | 115 °C (239 °F; 388 K) |
36.12 g/100 g (10°C) 62.07 g/100 g (15.5°C) 66.41 g/100 g (16°C)[1] | |
Solubility | 20.26 g/100 g (16°C, ethanol)[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Lithium azide is the lithium salt of hydrazoic acid. It is an unstable and toxic compound that decomposes into lithium and nitrogen when heated.
Preparation
It can be prepared by metathesis reaction between sodium azide and lithium nitrate or lithium sulfate solutions:
- NaN3 + LiNO3 → LiN3 + NaNO3
- 2NaN3 + Li2SO4 → 2LiN3 + Na2SO4[3]
It can also be prepared by reacting lithium sulfate with barium azide.
- Ba(N3)2 + Li2SO4 → 2LiN3 + BaSO4[1]
References
- 1 2 3 Hála, Jiri. "IUPAC-NIST Solubility Data Series. 79. Alkali and Alkaline Earth Metal Pseudohalides" (PDF). nist.gov. Retrieved 31 January 2018.
- ↑ Pringle, G. E.; Noakes, D. E. (February 1968). "The crystal structures of lithium, sodium and strontium azides". Acta Crystallogr. B. 24 (2): 262–269. doi:10.1107/S0567740868002062.
- ↑ http://www.lambdasyn.org/synfiles/lithiumazid.htm
Salts and covalent derivatives of the azide ion | |||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
HN3 | He | ||||||||||||||||||
LiN3 | Be(N3)2 | B(N3)3 | CH3N3, C(N3)4 |
N(N3)3,H2N—N3 | O | FN3 | Ne | ||||||||||||
NaN3 | Mg(N3)2 | Al(N3)3 | Si(N3)4 | P | SO2(N3)2 | ClN3 | Ar | ||||||||||||
KN3 | Ca(N3)2 | Sc(N3)3 | Ti(N3)4 | VO(N3)3 | Cr(N3)3, CrO2(N3)2 |
Mn(N3)2 | Fe(N3)3 | Co(N3)2, Co(N3)3 |
Ni(N3)2 | CuN3, Cu(N3)2 |
Zn(N3)2 | Ga(N3)3 | Ge | As | Se(N3)4 | BrN3 | Kr | ||
RbN3 | Sr(N3)2 | Y | Zr(N3)4 | Nb | Mo | Tc | Ru(N3)63− | Rh(N3)63− | Pd(N3)2 | AgN3 | Cd(N3)2 | In | Sn | Sb | Te | IN3 | Xe(N3)2 | ||
CsN3 | Ba(N3)2 | Hf | Ta | W | Re | Os | Ir(N3)63− | Pt(N3)62− | Au(N3)4− | Hg2(N3)2, Hg(N3)2 |
TlN3 | Pb(N3)2 | Bi(N3)3 |
Po | At | Rn | |||
Fr | Ra(N3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
↓ | |||||||||||||||||||
La | Ce(N3)3, Ce(N3)4 |
Pr | Nd | Pm | Sm | Eu | Gd(N3)3 | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||||
Ac | Th | Pa | UO2(N3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |
This article is issued from
Wikipedia.
The text is licensed under Creative Commons - Attribution - Sharealike.
Additional terms may apply for the media files.