Lithium iron phosphate battery

Lithium iron phosphate battery
Specific energy 90–110 Wh/kg (320–400 J/g or kJ/kg)
Energy density 220 Wh/L (790 kJ/L)
Specific power around 200 W/kg[1]
Energy/consumer-price 3.0–24 Wh/US$[2]
Time durability > 10 years
Cycle durability 2,000 cycles
Nominal cell voltage 3.2 V

The lithium iron phosphate (LiFePO
4) battery, also called LFP battery (with "LFP" standing for "lithium ferrophosphate"), is a type of rechargeable battery, specifically a lithium-ion battery, which uses LiFePO
4 as a cathode material, and a graphitic carbon electrode with a metallic current collector grid as the anode. The specific capacity of LiFePO
4 is higher than that of the related lithium cobalt oxide (LiCoO
2) chemistry, but its energy density is slightly lower due to its low operating voltage. The main problem of LiFePO
4 is its low electrical conductivity. Therefore, all the LiFePO
4 cathodes under consideration are actually LiFePO
4/C.[3] Because of low cost, low toxicity, well-defined performance, long-term stability, etc. LiFePO
4 is finding a number of roles in vehicle use, utility scale stationary applications, and backup power.

History

LiFePO
4 is a natural mineral of the olivine family (triphylite). Its use as a battery electrode which was first described in published literature by John B. Goodenough's research group at the University of Texas in 1996,[4][5] as a cathode material for rechargeable lithium batteries. Because of its low cost, non-toxicity, the natural abundance of iron, its excellent thermal stability, safety characteristics, electrochemical performance, and specific capacity (170 mA·h/g, or 610 C/g) it has gained considerable market acceptance.[6][7]

The chief barrier to commercialization was its intrinsically low electrical conductivity. This problem was overcome by reducing the particle size, coating the LiFePO
4 particles with conductive materials such as carbon nanotubes[8][9], or both. This approach was developed by Michel Armand and his coworkers.[10] Another approach by Yet Ming Chiang's group consisted of doping[6] LFP with cations of materials such as aluminium, niobium, and zirconium. Products are now in mass production and are used in industrial products by major corporations including Black and Decker's DeWalt brand, the Fisker Karma, Daimler AG, Cessna and BAE Systems.

MIT introduced a new coating that allows the ions to move more easily within the battery. The "Beltway Battery" utilizes a bypass system that allows the lithium ions to enter and leave the electrodes at a speed great enough to fully charge a battery in under a minute. The scientists discovered that by coating lithium iron phosphate particles in a glassy material called lithium pyrophosphate, ions bypass the channels and move faster than in other batteries. Rechargeable batteries store and discharge energy as charged atoms (ions) are moved between two electrodes, the anode and the cathode. Their charge and discharge rate are restricted by the speed with which these ions move. Such technology could reduce the weight and size of the batteries. A small prototype battery cell has been developed that can fully charge in 10 to 20 seconds, compared with six minutes for standard battery cells.[11]

Negative electrodes (anode, on discharge) made of petroleum coke were used in early lithium-ion batteries; later types used natural or synthetic graphite. [12]

Advantages and disadvantages

The LiFePO
4 battery uses a lithium-ion-derived chemistry and shares many advantages and disadvantages with other lithium-ion battery chemistries. However, there are significant differences.

LFP chemistry offers a longer cycle life than other lithium-ion approaches.[13]

Like nickel-based rechargeable batteries (and unlike other lithium ion batteries),[14] LiFePO
4 batteries have a very constant discharge voltage. Voltage stays close to 3.2 V during discharge until the cell is exhausted. This allows the cell to deliver virtually full power until it is discharged, and it can greatly simplify or even eliminate the need for voltage regulation circuitry.

Because of the nominal 3.2 V output, four cells can be placed in series for a nominal voltage of 12.8 V. This comes close to the nominal voltage of six-cell lead-acid batteries. And, along with the good safety characteristics of LFP batteries, this makes LFP a good potential replacement for lead-acid batteries in many applications such as automotive and solar applications, provided the charging systems are adapted not to damage the LFP cells through excessive charging voltages (beyond 3.6 volts DC per cell while under charge), temperature-based voltage compensation, equalisation attempts or continuous trickle charging. The LFP cells must be at least balanced initially before the pack is assembled and a protection system also needs to be implemented to ensure no cell can be discharged below a voltage of 2.5 V or severe damage will occur in most instances.

The use of phosphates avoids cobalt's cost and environmental concerns, particularly concerns about cobalt entering the environment through improper disposal,[13] as well as the potential for the thermal runaway characteristic of cobalt-content rechargeable lithium cells manifesting itself.

LiFePO
4 has higher current or peak-power ratings than LiCoO
2.[15]

The energy density (energy/volume) of a new LFP battery is some 14% lower than that of a new LiCoO
2 battery.[16] Also, many brands of LFPs, as well as cells within a given brand of LFP batteries, have a lower discharge rate than lead-acid or LiCoO
2. Since discharge rate is a percentage of battery capacity a higher rate can be achieved by using a larger battery (more ampere hours) if low-current batteries must be used. Better yet, a high current LFP cell (which will have a higher discharge rate than a lead acid or LiCoO
2 battery of the same capacity) can be used.

LiFePO
4 cells experience a slower rate of capacity loss (aka greater calendar-life) than lithium-ion battery chemistries such as LiCoO
2 cobalt or LiMn
2O
4 manganese spinel lithium-ion polymer batteries (LiPo battery) or lithium-ion batteries.[17] After one year on the shelf, a LiFePO
4 cell typically has approximately the same energy density as a LiCoO
2 Li-ion cell, because of LFP's slower decline of energy density.

Safety

One important advantage over other lithium-ion chemistries is thermal and chemical stability, which improves battery safety.[13] LiFePO
4 is an intrinsically safer cathode material than LiCoO
2 and manganese spinel, through omission of the cobalt, with its negative resistance versus increasing-heat property potentially encouraging thermal runaway. The Fe–P–O bond is stronger than the Co–O bond, so that when abused, (short-circuited, overheated, etc.) the oxygen atoms are much harder to remove. This stabilization of the redox energies also helps fast ion migration.[14]

As lithium migrates out of the cathode in a LiCoO
2 cell, the CoO
2 undergoes non-linear expansion that affects the structural integrity of the cell. The fully lithiated and unlithiated states of LiFePO
4 are structurally similar which means that LiFePO
4 cells are more structurally stable than LiCoO
2 cells.

No lithium remains in the cathode of a fully charged LiFePO
4 cell—in a LiCoO
2 cell, approximately 50% remains in the cathode. LiFePO
4 is highly resilient during oxygen loss, which typically results in an exothermic reaction in other lithium cells.[7]

As a result, lithium iron phosphate cells are much harder to ignite in the event of mishandling (especially during charge) although any fully charged battery can only dissipate overcharge energy as heat. Therefore, failure of the battery through misuse is still possible. It is commonly accepted that LiFePO
4 battery does not decompose at high temperatures.[13] The difference between LFP and the LiPo battery cells commonly used in the aeromodelling hobby is particularly notable.

Specifications

  • Cell voltage
    • Minimum discharge voltage = 2.5 V[18]
    • Working voltage = 3.0 ~ 3.3 V
    • Maximum charge voltage = 3.65 V
  • Volumetric energy density = 220 Wh/dm3 (790 kJ/dm3)
  • Gravimetric energy density > 90 Wh/kg[19] (> 320 J/g)
  • 100% DOD cycle life (number of cycles to 80% of original capacity) = 2,000–7,000[20]
  • 10% DOD cycle life (number of cycles to 80% of original capacity) > 10,000[21]
  • Sony Fortelion: 74% capacity after 8,000 cycles with 100% DOD[22]
  • Cathode composition (weight)
  • Cell configuration
  • Experimental conditions:
    • Room temperature
    • Voltage limits: 2.0–3.65 V
    • Charge: Up to C/1 rate up to 3.6 V, then constant voltage at 3.6 V until I < C/24
  • According to the manufacturer BYD the lithium iron phosphate battery of the electric car e6 is charged at a fast charging station to 80% within 15 minutes, and 100% within 40 minutes .[23]

Usage

Transportation

Higher discharge rates needed for acceleration, lower weight and longer life makes this battery type ideal for bicycles and electric cars. 12V LiFePO4 batteries are also getting popularity as a second (house) battery for a caravan, motor-home or boat.

Solar garden and security light systems

Single "14500" (AA battery–sized) LFP cells are now used in some solar-powered path lights instead of 1.2 V NiCd/NiMH.

LFP's higher (3.2 V) working voltage can allow a single cell to drive an LED without needing a step-up circuit. The increased tolerance to modest overcharging (compared to other Li cell types) means that LiFePO
4 could be connected to photovoltaic cells without complex circuitry. A single LFP cell also alleviates corrosion, condensation and dirt issues associated with battery holder and cell-to-cell contacts – such poor connections often especially plague outdoor systems using multiple removable NiMH cells.

More sophisticated LFP solar charged passive infrared security lamps are also emerging (2013). As AA-sized LFP cells have a capacity of only 600 mA⋅h (while the lamp's bright LED may draw 60 mA) only 10 hours' run time may be expected. However – if triggering is only occasional – such systems may cope even under low-sunlight charging conditions, as lamp electronics ensure after dark "idle" currents of under 1 mA.

LiFePO
4-powered solar lamps are visibly brighter than ubiquitous outdoor solar lights, and performance overall is considered more reliable.

Other uses

Many home EV conversions use the large format versions as the car's traction pack. With the efficient power-to-weight ratios, high safety features and the chemistry's refusal to go into thermal runaway, there are few barriers for use by amateur home "makers". Motorhomes are often converted to Lithium iron phosphate because of the high draw.

Some electronic cigarettes use these types of batteries.

Three torch/flashlight manufacturers (Imecs Corporation with wireless LiFePO
4 Battery Technology, Mag Instruments and LED Lenser) have products which use these batteries.

RC models may use these batteries, especially as RX and TX packs as a direct replacement of NiMh packs or LiPo packs without need for voltage regulator, as they provide 6.6 V nominal voltage over 7.4 V of LiPo packs, which is little higher and may require to be regulated down to 6.0 V.

Celestron has come out with a lightweight "PowerTank Lithium" battery that uses this chemistry to power their telescope drives. It weighs only 2.25 pounds (1.02 kg) and produces 84.6 W⋅h and 12 V DC. Additionally, the internal battery in some of their telescope mounts uses this chemistry.

Conspec Controls has come out with and has had independently IECeX 60079-0 & 60079-11 certified by MSTC Mine Safety Technology Center in Australia an "Intrinsically Safe Gateway", an Intelligent Power and Communications Gateway with a built in UPS which uses this battery chemistry to provide a stable 4800mAh of 18V 500mA Instrisically Safe Power for a network of Intrinsically Safe Gas Monitoring Sensors for use in underground coal mines. This new technology has now been successfully deployed at Glencore's Ulan's Number 3 and West Longwall Coal Mines in the Western Coalfields of New South Wales, Australia. Additionally, Conspec Controls uses this battery technology to power their wireless intrinsically safe remote gas monitors as a means of extending traditional underground gas monitoring systems in underground coal mines from the end of a wired network backbone to the longwall face. [24]

See also

References

  1. ↑ "Archived copy" (PDF). Archived (PDF) from the original on 2016-09-21. Retrieved 2016-04-20.
  2. ↑ "Lithium Iron Phosphate Battery Suppliers and Manufacturers". Alibaba.com. Archived from the original on 2014-06-09.
  3. ↑ Eftekhari, Ali (2017). "LiFePO
    4    /C Nanocomposites for Lithium-Ion Batteries"    . J. Power Sources. 343: 395–411. Bibcode:2017JPS...343..395E. doi:10.1016/j.jpowsour.2017.01.080.
  4. ↑ "LiFePO
    4    : A Novel Cathode Material for Rechargeable Batteries"     Archived 2017-05-10 at the Wayback Machine., A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, Electrochimical Society Meeting Abstracts, 96-1, May, 1996, pp 73
  5. ↑ A.K. Padhi; K.S. Nanjundaswamy & J.B. Goodenough (1997). "Phospho-olivines as positive-electrode materials for rechargeable lithium batteries". J. Electrochem. Soc. 144: 1188–1194. doi:10.1149/1.1837571.
  6. 1 2 "Bigger, Cheaper, Safer Batteries: New material charges up lithium-ion battery work". Archived from the original on 2008-04-13. sciencenews.org
  7. 1 2 "Building safer Li ion batteries". houseofbatteries.com. Archived from the original on 2011-01-31.
  8. ↑ Susantyoko, Rahmat Agung; Karam, Zainab; Alkhoori, Sara; Mustafa, Ibrahim; Wu, Chieh-Han; Almheiri, Saif (2017). "A surface-engineered tape-casting fabrication technique toward the commercialisation of freestanding carbon nanotube sheets". Journal of Materials Chemistry A. 5 (36): 19255–19266. doi:10.1039/c7ta04999d. ISSN 2050-7488.
  9. ↑ Susantyoko, Rahmat Agung; Alkindi, Tawaddod Saif; Kanagaraj, Amarsingh Bhabu; An, Boohyun; Alshibli, Hamda; Choi, Daniel; AlDahmani, Sultan; Fadaq, Hamed; Almheiri, Saif (2018). "Performance optimization of freestanding MWCNT-LiFePO4 sheets as cathodes for improved specific capacity of lithium-ion batteries". RSC Advances. 8 (30): 16566–16573. doi:10.1039/c8ra01461b. ISSN 2046-2069.
  10. ↑ Armand, Michel; Goodenough, John B.; Padhi, Akshaya K.; Nanjundaswam, Kirakodu S.; Masquelier, Christian (Feb 4, 2003), Cathode materials for secondary (rechargeable) lithium batteries, archived from the original on 2016-04-02, retrieved 2016-02-25
  11. ↑ "New Battery Technology Charges in Seconds". Archived from the original on 2012-08-02.
  12. ↑ David Linden (ed.), Handbook of Batteries 3rd Edition,McRaw Hill 2002, ISBN 0-07-135978-8, pages 35-16 and 35-17
  13. 1 2 3 4 "Rechargeable Lithium Batteries". Archived from the original on 2011-07-14. Electropaedia- Battery and Energy Technologies
  14. 1 2 "Harding Energy | Lithium Ion batteries | Lithium Polymer | Lithium Iron Phosphate". Harding Energy. Archived from the original on 2016-03-29. Retrieved 2016-04-06.
  15. ↑ A Better Battery? The Lithium Ion Cell Gets Supercharged Archived 2013-10-23 at the Wayback Machine., Adam Hadhazy , Scientific American, 2009-03-11.
  16. ↑ Guo, Y.; Hu, J.; Wan, L. "Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices. Adv Mater 2008; 20, 2878–2887
  17. ↑ A123Systems Archived 2012-03-01 at the Wayback Machine. "...Current test projecting excellent calendar life: 17% impedance growth and 23% capacity loss in 15 [fifteen!] years at 100% SOC, 60 deg. C..."
  18. ↑ "CA40". CALB. Archived from the original on 2014-10-09.
  19. ↑ "Large-Format, Lithium Iron Phosphate – After Gutenberg". Jcwinnie.biz. Archived from the original on 2008-11-18. Retrieved 2012-04-24.
  20. ↑ http://www.a123systems.com/technology/life%5Bpermanent+dead+link%5D
  21. ↑ GWL-Power: Winston 90Ah over 10.000 /13.000 cycles Archived 2013-10-04 at the Wayback Machine., PDF, 21. February 2012.
  22. ↑ Sony Fortelion page 13 Archived 2015-02-06 at the Wayback Machine., PDF, included at 3. January 2015.
  23. ↑ byd-auto.net Archived 2016-02-06 at the Wayback Machine. Website of BYD: 40(min) / 15(min 80%)
  24. ↑ "IECEx System". iecex.iec.ch. Retrieved 2018-08-26.
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