Chlorophyll ''f''
 | |
| Names | |
|---|---|
| IUPAC name
[methyl 14-ethyl-8-formyl-4,13,18-trimethyl-20-oxo-3-{3-oxo-3-[(3,7,11,15-tetramethylhexadec-2-en-1-yl)oxy]propyl}-9-vinylphorbine-21-carboxylatato(2−)-κ4N23,N24,N25,N26]magnesium | |
| Identifiers | |
3D model (JSmol) |
|
| ChEBI | |
PubChem CID |
|
| |
| |
| Properties | |
| C55H70O6N4Mg[1] | |
| Molar mass | 907.4725 g/mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Chlorophyll f is a type form of chlorophyll that absorbs further in the red (infrared light) than other chlorophylls.[2][3] In 2010, it was reported from stromatolites from Western Australia's Shark Bay.[4]
The finding was made by scientists at the University of Sydney led by Professor Min Chen, and is the first discovery of a new form of chlorophyll in 60 years.[4] However, the function of chlorophyll f in photosynthetic reactions is uncertain and the ecological distribution of chlorophyll f remains unknown.
Based on NMR data, optical and mass spectra and density functional theory (DFT) simulation, it is confirmed to have a structure of C55H70O6N4Mg or [2-formyl]-chlorophyll a.[1][2]
References
- 1 2 Willows, Robert D.; Li, Yaqiong; Scheer, Hugo; Chen, Min (15 March 2013). "Structure of chlorophyll f". Organic Letters. doi:10.1021/ol400327j.
- 1 2 Chen, M. .; Schliep, M. .; Willows, R. D.; Cai, Z. -L.; Neilan, B. A.; Scheer, H. . (2010). "A Red-Shifted Chlorophyll". Science. 329 (5997): 1318–1319. Bibcode:2010Sci...329.1318C. doi:10.1126/science.1191127. PMID 20724585.
- ↑ Ferris Jabr (August 19, 2010). "A New Form of Chlorophyll?". Scientific American. Retrieved 2010-09-07.
- 1 2 "Australian scientists discover first new chlorophyll in 60 years". University of Sydney. 20 August 2010.
This article is issued from
Wikipedia.
The text is licensed under Creative Commons - Attribution - Sharealike.
Additional terms may apply for the media files.