2,3-diketo-5-methylthiopentyl-1-phosphate enolase

2,3-diketo-5-methylthiopentyl-1-phosphate enolase
Identifiers
EC number 5.3.2.5
Databases
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB structures RCSB PDB PDBe PDBsum

2,3-diketo-5-methylthiopentyl-1-phosphate enolase (EC 5.3.2.5, DK-MTP-1-P enolase, MtnW, YkrW, RuBisCO-like protein, RLP) is an enzyme with systematic name 2,3-diketo-5-methylthiopentyl-1-phosphate keto-enol-isomerase.[1][2] This enzyme catalyses the following chemical reaction

5-(methylthio)-2,3-dioxopentyl phosphate 2-hydroxy-5-(methylthio)-3-oxopent-1-enyl phosphate

The enzyme participates in the methionine salvage pathway in Bacillus subtilis.

References

  1. Myers RW, Wray JW, Fish S, Abeles RH (November 1993). "Purification and characterization of an enzyme involved in oxidative carbon-carbon bond cleavage reactions in the methionine salvage pathway of Klebsiella pneumoniae". The Journal of Biological Chemistry. 268 (33): 24785–91. PMID 8227039.
  2. Ashida H, Saito Y, Kojima C, Kobayashi K, Ogasawara N, Yokota A (October 2003). "A functional link between RuBisCO-like protein of Bacillus and photosynthetic RuBisCO". Science. 302 (5643): 286–90. doi:10.1126/science.1086997. PMID 14551435.
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