Trihydroxypterocarpan dimethylallyltransferase

Trihydroxypterocarpan dimethylallyltransferase (EC 2.5.1.36, glyceollin synthase, dimethylallylpyrophosphate:3,6a,9-trihydroxypterocarpan dimethylallyltransferase, dimethylallylpyrophosphate:trihydroxypterocarpan dimethylallyl transferase, dimethylallyl-diphosphate:(6aS,11aS)-3,6a,9-trihydroxypterocarpan dimethyltransferase) is an enzyme with systematic name dimethylallyl-diphosphate:(6aS,11aS)-3,6a,9-trihydroxypterocarpan dimethylallyltransferase.[1][2] This enzyme catalyses the following chemical reaction

(1) dimethylallyl diphosphate + (6aS,11aS)-3,6a,9-trihydroxypterocarpan diphosphate + 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan
(2) dimethylallyl diphosphate + (6aS,11aS)-3,6a,9-trihydroxypterocarpan diphosphate + 4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan
Trihydroxypterocarpan dimethylallyltransferase
Identifiers
EC number2.5.1.36
CAS number70851-94-4
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum

Part of the glyceollin biosynthesis system in soy bean.

References

  1. Leube J, Grisebach H (1983). "Further studies on induction of enzymes of phytoalexin synthesis in soybean and cultured soybean cells". Z. Naturforsch. C: Biosci. 38: 730–735.
  2. Zähringer U, Schaller E, Grisebach H (1981). "Induction of phytoalexin synthesis in soybean. Structure and reactions of naturally occurring and enzymatically prepared prenylated pterocarpans from elicitor-treated cotyledons and cell cultures of soybean". Z. Naturforsch. C. 36: 234–241.
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