Partition function (quantum field theory)

The n-point correlation functions ${\displaystyle G_{n}}$ can be expressed using the path integral formalism as

${\displaystyle G_{n}(x_{1},...,x_{n})\equiv \langle \Omega |T\{\phi (x_{1})\cdots \phi (x_{n})\}|\Omega \rangle ={\frac {\int {\mathcal {D}}\phi \,\phi (x_{1})\cdots \phi (x_{n})\exp(iS[\phi ]/\hbar )}{\int {\mathcal {D}}\phi \,\exp(iS[\phi ]/\hbar )}}}$

where the left-hand side is the time-ordered product used to calculate S-matrix elements. The ${\displaystyle {\mathcal {D}}\phi }$ on the right-hand side means integrate over all possible classical field configurations ${\displaystyle \phi (x)}$ with a phase given by the classical action ${\displaystyle S[\phi ]}$ evaluated in that field configuration.[1]

The generating functional ${\displaystyle Z[J]}$ can be used to calculate the above path integrals using an auxiliary function ${\displaystyle J}$ (called current in this context).

From the definition (in a 4D context)

${\displaystyle Z[J]=\int {\mathcal {D}}\phi \exp \left\{{\frac {i}{\hbar }}\left[S[\phi ]+\int d^{4}xJ(x)\phi (x))\right]\right\}}$

it can be seen using functional derivatives that the n-point correlation functions ${\displaystyle G_{n}(x_{1},...,,x_{n})}$ are given by

${\displaystyle G_{n}(x_{1},...,x_{n})=(-i\hbar )^{n}{\frac {1}{Z[0]}}\left.{\frac {\partial ^{n}Z}{\partial J(x_{1})\cdots \partial J(x_{n})}}\right|_{J=0}}$

The generating functional is the quantum field theory analog of the partition function in statistical mechanics: it tells us everything we could possibly want to know about a system. The generating functional is the holy grail of any particular field theory: if you have an exact closed-form expression for ${\displaystyle Z[J]}$ for a particular theory, you have solved it completely.[2]

Unlike the partition function in statistical mechanics, the partition function in quantum field theory contains an extra factor of i in front of the action, making the integrand complex, not real. This i points to a deep connection between quantum field theory and the statistical theory of fields. This connection can be seen by Wick rotating the integrand in the exponential of the path integral.[3] The i arises from the fact that the partition function in QFT calculates quantum-mechanical probability amplitudes between states, which take on values in a complex projective space (complex Hilbert space, but the emphasis is placed on the word projective, because the probability amplitudes are still normalized to one). The fields in statistical mechanics are random variables that are real-valued as opposed to operators on a Hilbert space.

• Jean Zinn-Justin (2009), Scholarpedia, 4(2): 8674.
• Kleinert, Hagen, Path Integrals in Quantum Mechanics, Statistics, Polymer Physics, and Financial Markets, 4th edition, World Scientific (Singapore, 2004); paperback ISBN 981-238-107-4 (also available online: PDF-files).