Vinyldiphenylphosphine
Names | |
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IUPAC name
ethenyl(diphenyl)phosphane | |
Other names
Diphenylvinylphosphine | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
EC Number | 218-459-2 |
PubChem CID |
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Properties | |
C14H13P | |
Molar mass | 212.23 g·mol−1 |
Appearance | colorless solid |
Melting point | 70.5–71.5 °C (158.9–160.7 °F; 343.6–344.6 K) |
Boiling point | 104 °C (219 °F; 377 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Vinyldiphenylphosphine is the organophosphorus compound with the formula (C6H5)2PCH=CH2. This colorless, air-sensitive solid is used as a precursor to ligands used in coordination chemistry and homogeneous catalysis. It is prepared by treating chlorodiphenylphosphine with vinyl Grignard reagents.[1]
References
- ↑ Rabinowitz, Robert; Pellon, Joseph (1961). "Phosphorus-containing monomers. I. Synthesis of Vinyl Phosphines, Oxides, Sulfides, and Phosphonium Compounds". Journal of Organic Chemistry. 26 (11): 4623–6. doi:10.1021/jo01069a101.
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