Ultra high temperature ceramic matrix composite

Ultra-high temperature ceramic matrix composites (UHTCMC) or Ultra-high Temperature Ceramic Composites (UHTCC) are a class of refractory ceramic matrix composites (CMCs), the motivation to develop UHTCMCs is to overcome the limits associated with the bulk UHTCs like ZrB2, HfB2, or their composites due to a catastrofic fracture easily under mechanical or thermo-mechanical loads because of cracks initiated by small defects or scratches. The European Commission funded a research project, C3HARME,[1] under the NMP-19-2015 call of Framework Programmes for Research and Technological Development in 2016 (still ongoing) for the design, development, production and testing of a new class of ultra-refractory ceramic matrix composites reinforced with silicon carbide fibers and Carbon fibers suitable for applications in severe aerospace environments as possible near-zero ablation thermal protection system (TPS) materials (e.g heat shield) and for propulsion (e.g. rocket nozzle).[2] The demand for reusable advanced materials with temperature capability over 2000°C has growing.[3] Recently carbon fiber reinforced zirconium boride-based composites obtained by slurry infiltration (SI) and sintering has been investigated.[4][5][6][7][8][9][10][11]


Breakthroughs in research

The European Commission funded a research project, C3HARME, under the NMP-19-2015 call of Framework Programmes for Research and Technological Development in 2016 (still ongoing) for the design, development, production and testing of a new class of ultra-refractory ceramic matrix composites reinforced with silicon carbide fibers and Carbon fiberssuitable for applications in severe aerospace environments.[12]

References

  1. [www.c3harme.eu "c³harme"] Check |url= value (help). www.c3harme.eu.
  2. Sciti, D.; Zoli, L.; Silvestroni, L.; Cecere, A.; Martino, G.D. Di; Savino, R. "Design, fabrication and high velocity oxy-fuel torch tests of a C f -ZrB 2 - fiber nozzle to evaluate its potential in rocket motors". Materials & Design. 109: 709–717. doi:10.1016/j.matdes.2016.07.090.
  3. Sziroczak, D.; Smith, H. "A review of design issues specific to hypersonic flight vehicles". Progress in Aerospace Sciences. 84: 1–28. doi:10.1016/j.paerosci.2016.04.001.
  4. Zoli, L.; Sciti, D. "Efficacy of a ZrB2 –SiC matrix in protecting C fibres from oxidation in novel UHTCMC materials". Materials & Design. 113: 207–213. doi:10.1016/j.matdes.2016.09.104.
  5. Zoli, L.; Vinci, A.; Silvestroni, L.; Sciti, D.; Reece, M.; Grasso, S. "Rapid spark plasma sintering to produce dense UHTCs reinforced with undamaged carbon fibres". Materials & Design. 130: 1–7. doi:10.1016/j.matdes.2017.05.029.
  6. Galizia, Pietro; Failla, Simone; Zoli, Luca; Sciti, Diletta. "Tough salami-inspired Cf/ZrB2 UHTCMCs produced by electrophoretic deposition". Journal of the European Ceramic Society. 38 (2): 403–409. doi:10.1016/j.jeurceramsoc.2017.09.047.
  7. Vinci, Antonio; Zoli, Luca; Sciti, Diletta; Melandri, Cesare; Guicciardi, Stefano. "Understanding the mechanical properties of novel UHTCMCs through random forest and regression tree analysis". Materials & Design. 145: 97–107. doi:10.1016/j.matdes.2018.02.061.
  8. Zoli, L.; Medri, V.; Melandri, C.; Sciti, D. "Continuous SiC fibers-ZrB2 composites". Journal of the European Ceramic Society. 35 (16): 4371–4376. doi:10.1016/j.jeurceramsoc.2015.08.008.
  9. Sciti, D.; Murri, A. Natali; Medri, V.; Zoli, L. "Continuous C fibre composites with a porous ZrB2 Matrix". Materials & Design. 85: 127–134. doi:10.1016/j.matdes.2015.06.136.
  10. Sciti, D.; Pienti, L.; Murri, A. Natali; Landi, E.; Medri, V.; Zoli, L. "From random chopped to oriented continuous SiC fibers–ZrB2 composites". Materials & Design. 63: 464–470. doi:10.1016/j.matdes.2014.06.037.
  11. Vinci, Antonio; Zoli, Luca; Sciti, Diletta (September 2018). "Influence of SiC content on the oxidation of carbon fibre reinforced ZrB2 /SiC composites at 1500 and 1650 °C in air". Journal of the European Ceramic Society. 38 (11): 3767–3776. doi:10.1016/j.jeurceramsoc.2018.04.064. ISSN 0955-2219.
  12. "C3HARME".
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