Triafulvalene

Triafulvalene
Names
Other names
[1,1'-Bi(cyclopropylidene)]-2,2'-diene
1,1'-Bi(cycloprop-2-en-1-ylidene)
Identifiers
3D model (JSmol)
Properties
C6H4
Molar mass 76.10 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Triafulvalene or cyclopropenylidenecyclopropene is a fulvalenes hydrocarbon with chemical formula C6H4, composed of two linked cyclopropene rings. Triafulvalene has never been isolated.[1] It will decomposed via Isodesmic reaction.[2] But this molecule was of tremendous interest for many theoretical organic chemists.[3] People have studied the structure, stability and spectra of this special compound.[4]

See also

References

  1. Carey, Francis A.; Richard J. Sundberg (2007). Advanced Organic Chemistry Part A: Structure and Mechanisms. Springer Science & Business Media. pp. 755–787. ISBN 0-387448-99-3.
  2. Neuenschwander, Markus (1986), "Synthetic and NMR spectroscopic investigations of fulvenes and fulvalenes" (PDF), Pure Appl. Chem., 58 (1): 55–66
  3. J. Org. Chem., 1997, 62 (7), pp 2026–2038
  4. Article · December 2015 DOI: 10.13179/canchemtrans.2015.03.04.0241


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