Thiepane

Thiepane
Structural formula of thiepane
Ball-and-stick model of the thiepane molecule
Names
IUPAC name
Thiepane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.022.981
EC Number 225-279-8
Properties
C6H12S
Molar mass 116.22 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Thiepane is the organosulfur compound with the formula (CH2)6S. Thiepanes are seven-membered ring heterocycles that contains sulfide.[1] The parent thiepane has seldom been studied.

A variety of derivatives are known. Hexathiathiepane (CAS RN 17233-71-5, m.p. 90 °C) is CH2S6.[2] A naturally occurring derivative is lenthionine, 1,4-(CH2)2S5.

Reference

  1. Yamamoto, Kagetoshi; Yamazaki, Shoko (1996). "Thiepanes and thiepins". In Newkome, George R. Comprehensive Heterocyclic Chemistry II. 9. pp. 67–111. doi:10.1016/B978-008096518-5.00211-2.
  2. Fehér, F.; Lex, J. (1976). "Kristall- und Molecülstrukturen von Hexathiepan (S6CH2), Pentathiepan (S5CH2) und Dibenzylpentathian (S5C(CH2C6H5)2)". Z. anorg. allg. Chem. 423: 103–111. doi:10.1002/zaac.19764230203.
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