Rajendra Rathore (chemist)

Rajendra Rathore (December 12, 1961 – February 16, 2018) was an organic chemist and professor at Marquette University in Milwaukee, Wisconsin as Pfletschinger-Habermann professor of organic chemistry.[1] He made important contributions in the area of supramolecular chemistry,[2][3] synthesis of novel electro-active molecules,[4] and drug discovery.[5][6] Rathore died on February 16, 2018.[7][8]

Education

Rajendra Rathore received his M.Sc. from the Indian Institute of Technology Kanpur in 1986. He earned Ph.D. in organic chemistry from the University of Western Ontario in London, Canada in 1990. He was a post-doctoral research associate and then a visiting assistant professor during 1992-2000 at the University of Houston under the supervision of Jay Kochi.[9] Rajendra Rathore joined the faculty at Marquette University in 2000.

Research

Synthesis of pillarene

In 1995 Rathore and Kochi reported a synthetic procedure to produce various diarylmethanes from their corresponding benzyl methyl ethers.[10] They showed that transformation of bis(methoxymethyl)-p-hydroquinone ether yields corresponding diarylmethane and a polymeric-like material. A reanalysis of this polymeric material showed that it consisted mainly from pillararene.[11] A full characterization of pillararene was first reported in 2008 by Tomoki Ogoshi et al.[12]

Personal Life

Rajendra Rathore was born in Kannauj, India in 1961. In college in Kanpur, India, he met his wife, Rajni. Raj was a devoted husband and father of two girls. He enjoyed cooking and throwing dinner parties for his friends and family.

References

  1. ↑ Rajendra Rathore Biography. Marquette University
  2. ↑ Rathore, Rajendra; Burns, Carrie L. (May 2003). "A Practical One-Pot Synthesis of Soluble Hexa-peri-hexabenzocoronene and Isolation of Its Cation-Radical Salt". The Journal of Organic Chemistry. 68 (10): 4071–4074. doi:10.1021/jo034271e.
  3. ↑ Navale, Tushar S.; Ivanov, Maxim V.; Hossain, Mohammad M.; Rathore, Rajendra (15 January 2018). "FHBC, a Hexa-peri-hexabenzocoronene-Fluorene Hybrid: A Platform for Highly Soluble, Easily Functionalizable HBCs with an Expanded Graphitic Core". Angewandte Chemie International Edition. 57 (3): 790–794. doi:10.1002/anie.201711739. PMID 29194947.
  4. ↑ Rathore, Rajendra; Abdelwahed, Sameh H.; Guzei, Ilia A. (July 2003). "Synthesis, Structure, and Evaluation of the Effect of Multiple Stacking on the Electron-Donor Properties of π-Stacked Polyfluorenes". Journal of the American Chemical Society. 125 (29): 8712–8713. doi:10.1021/ja035518s.
  5. ↑ Ramchandran, Ramani; Sem, Daniel; Rathore, Rajendra. "US Patent Application for SMALL MOLECULE ANTAGONISTS OF DUSP5 AND METHODS OF USE Patent Application (Application #20180000778 issued January 4, 2018) - Justia Patents Search". patents.justia.com. Retrieved 31 May 2018.
  6. ↑ "Milwaukee doctor imagines better umbilical cord clamp". Retrieved 31 May 2018.
  7. ↑ "Klingler College of Arts and Sciences 2018 Awards". medium.com. 19 April 2018. Retrieved 31 May 2018.
  8. ↑ "Rajendra Rathore « Krause Funeral Home". www.krausefuneralhome.com.
  9. ↑ Rathore, Rajendra (17 November 2008). "Jay Kazuo Kochi (1927-2008)". Angewandte Chemie International Edition. 47 (48): 9186–9186. doi:10.1002/anie.200805187.
  10. ↑ Rathore, Rajendra; Kochi, Jay K. (November 1995). "Radical-Cation Catalysis in the Synthesis of Diphenylmethanes via the Dealkylative Coupling of Benzylic Ethers". The Journal of Organic Chemistry. 60 (23): 7479–7490. doi:10.1021/jo00128a020.
  11. ↑ Ivanov, Maxim V.; Wang, Denan; Navale, Tushar S.; Lindeman, Sergey V.; Rathore, Rajendra (19 February 2018). "From Intramolecular (Circular) in an Isolated Molecule to Intermolecular Hole Delocalization in a Two-Dimensional Solid-State Assembly: The Case of Pillarene". Angewandte Chemie International Edition. 57 (8): 2144–2149. doi:10.1002/anie.201712159. PMID 29327390.
  12. ↑ Ogoshi, Tomoki; Kanai, Suguru; Fujinami, Shuhei; Yamagishi, Tada-aki; Nakamoto, Yoshiaki (April 2008). "-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid Catalyzed Synthesis and Host–Guest Property". Journal of the American Chemical Society. 130 (15): 5022–5023. doi:10.1021/ja711260m.
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