Intermetallic particle

Intermetallic particles form during solidification of metallic alloys.

Aluminium alloys

Al-Si-Cu-Mg alloys

For example, Al-Si-Cu-Mg alloys form Al5FeSi- plate like intermetallic phase, Chinese script like -Al8Fe2Si, Al2Cu, etc. The size and morphology of these intermetallic phases in these alloys control the mechanical properties of these alloys especially strength and ductility.^[1] The size of these phases depends on the secondary dendrite arm spacing,^[2] as well as the Si content of the alloy,^[3]^[4]^[5]^[6]^[7] of the primary phase in the micro structure.

Phases and crystal structures

Phase	Structure	Space Group	a	b	c	α	β	γ	..
α-Al8Fe2Si^[8]	hexagonal	p63/mmc(194)	12.404	12.404	26.234	90	90	120	..
β-Al5FeSi^[9]	monoclinic	2/m	6.16760	6.1661	20.8093	..	..	91	..
Al2Cu	..	..	..	..	..	..	..	..	..
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Magnesium alloys

WE 43

In-situ synchrotron diffraction experiment^[10] on Electron alloy-WE 43 (Mg4Y3Nd) shows that this alloy form the following intermetallic phases ;Mg12Nd, Mg14Y4Nd,and Mg24Y5.

Phases and crystal structures

Phase	Structure	Space Group	a	b	c	α	β	γ	..
Mg41Nd5	..	..	..	..	..	..	..	..	..
β-Mg14Nd2Y^[11]	face centered cubic		2.2 nm			..	..		..
Mg24Y5^[11]	body centered cubic	..	1.12 nm	..	..	..	..	..	..
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AZ 91

Phases and crystal structures

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References

↑ Caceres, C. H. Svensson, I. L. Taylor, J. A. "Strength-ductility behaviour of Al-Si-Cu-Mg casting alloys in T6 temper" (5).
↑ Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (9 May 2013). "Alloy Composition and Dendrite Arm Spacing in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 44 (9): 4071–4080. Bibcode:2013MMTA...44.4071S. doi:10.1007/s11661-013-1768-x.
↑ Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (July 2013). "Effect of Si Content on the Size of Fe-Rich Intermetallic Particles in Al-xSi-0.8Fe Alloys". Materials Science Forum. 765: 107–111. doi:10.4028/www.scientific.net/MSF.765.107.
↑ "Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys". Shape/Tiryakioǧlu: 137–143. doi:10.1002/9781118888100.ch17.
↑ "Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys". Shape/Tiryakioǧlu: 137–143. doi:10.1002/9781118888100.ch17.
↑ "Ductility and solidification issues in Al-Si-Cu-Mg alloys". doi:10.14264/uql.2015.91.
↑ Sivarupan, Tharmalingam; Taylor, John Andrew; Cáceres, Carlos Horacio (25 February 2015). "SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 46 (5): 2082–2107. Bibcode:2015MMTA...46.2082S. doi:10.1007/s11661-015-2808-5.
↑ R.N. Corby and P.J. Black: Acta Crystallogr. Sect. B, 1977, vol. 33, pp. 3468–75.
↑ V. Hansen, B. Hauback, M. Sundberg, C. Romming, and J. Gjonnes: Acta Crystallogr. Sect. B, 1998, vol. 54, pp. 351–57.
↑ Tolnai, D.; Mendis, C.L.; Stark, A.; Szakács, G.; Wiese, B.; Kainer, K.U.; Hort, N. (July 2013). "In situ synchrotron diffraction of the solidification of Mg4Y3Nd". Materials Letters. 102-103: 62–64. doi:10.1016/j.matlet.2013.03.110.
1 2 http://www.journalamme.org/papers_vol21_1/1385S.pdf

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[International_Journal_of_Cast_Metals_Research-1] Caceres, C. H. Svensson, I. L. Taylor, J. A. "Strength-ductility behaviour of Al-Si-Cu-Mg casting alloys in T6 temper" (5).

[Metallurgical_and_Materials_Transactions_A-2] Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (9 May 2013). "Alloy Composition and Dendrite Arm Spacing in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 44 (9): 4071–4080. Bibcode:2013MMTA...44.4071S. doi:10.1007/s11661-013-1768-x.

[3] Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (July 2013). "Effect of Si Content on the Size of Fe-Rich Intermetallic Particles in Al-xSi-0.8Fe Alloys". Materials Science Forum. 765: 107–111. doi:10.4028/www.scientific.net/MSF.765.107.

[4] "Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys". Shape/Tiryakioǧlu: 137–143. doi:10.1002/9781118888100.ch17.

[5] "Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys". Shape/Tiryakioǧlu: 137–143. doi:10.1002/9781118888100.ch17.

[6] "Ductility and solidification issues in Al-Si-Cu-Mg alloys". doi:10.14264/uql.2015.91.

[7] Sivarupan, Tharmalingam; Taylor, John Andrew; Cáceres, Carlos Horacio (25 February 2015). "SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 46 (5): 2082–2107. Bibcode:2015MMTA...46.2082S. doi:10.1007/s11661-015-2808-5.

[8] R.N. Corby and P.J. Black: Acta Crystallogr. Sect. B, 1977, vol. 33, pp. 3468–75.

[9] V. Hansen, B. Hauback, M. Sundberg, C. Romming, and J. Gjonnes: Acta Crystallogr. Sect. B, 1998, vol. 54, pp. 351–57.

[10] Tolnai, D.; Mendis, C.L.; Stark, A.; Szakács, G.; Wiese, B.; Kainer, K.U.; Hort, N. (July 2013). "In situ synchrotron diffraction of the solidification of Mg4Y3Nd". Materials Letters. 102-103: 62–64. doi:10.1016/j.matlet.2013.03.110.

[journalamme.org-11] 1 2 http://www.journalamme.org/papers_vol21_1/1385S.pdf

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