Flavonol-3-O-triglucoside O-coumaroyltransferase

Flavonol-3-O-triglucoside O-coumaroyltransferase
Identifiers
EC number 2.3.1.173
Databases
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB structures RCSB PDB PDBe PDBsum

In enzymology, a flavonol-3-O-triglucoside O-coumaroyltransferase (EC 2.3.1.173) is an enzyme that catalyzes the chemical reaction

4-coumaroyl-CoA + a flavonol 3-O-[beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)-beta-D-glucoside] CoA + a flavonol 3-O-[6-(4-coumaroyl)-beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)- beta-D-glucoside]

The 3 substrates of this enzyme are 4-coumaroyl-CoA, flavonol, and [[3-O-beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)-beta-D-glucoside]], whereas its 4 products are CoA, flavonol, [[3-O-[6-(4-coumaroyl)-beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)-]], and beta-D-glucoside].

This enzyme belongs to the family of transferases, to be specific those acyltransferases transferring groups other than aminoacyl groups. The systematic name of this enzyme class is 4-coumaroyl-CoA:flavonol-3-O-[beta-D-glucosyl-(1->2)-beta-D-glucosid e] 6-O-4-coumaroyltransferase.

References

    • Saylor MH, Mansell RL (1977). "Hydroxycinnamoyl: coenzyme A transferase involved in the biosynthesis of kaempferol-3-(p-coumaroyl triglucoside) in Pisum sativum". Z. Naturforsch. C. 32 (9–10): 764&ndash, 8. PMID 145116.


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