Dichloro(1,5‐cyclooctadiene)palladium

Dichloro(1,5‐cyclooctadiene)palladium
Identifiers
CAS Number	12107-56-1 ;
3D model (JSmol)	Interactive image;
ChemSpider	4642864;
EC Number	235-161-8
PubChem CID	5702536;
	InChI InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; Key: RRHPTXZOMDSKRS-PHFPKPIQSA-L;
	SMILES C1CC=CCCC=C1.Cl[Pd]Cl;
Properties
Chemical formula	C8H12Cl2Pd
Molar mass	285.50 g·mol−1
Appearance	yellow solid
Density	2.045 g/cm3
Melting point	210 °C (410 °F; 483 K)
Hazards
GHS pictograms
GHS signal word	Warning
GHS hazard statements	H315, H319, H335
GHS precautionary statements	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Dichloro(1,5‐cyclooctadiene)palladium is the organopalladium compound with the formula PdCl₂(C₈H₁₂) where C₈H₁₂ is 1,5-cyclooctadiene. It is a yellow solid that is soluble in chloroform.^[1] According to X-ray crystallography, the Pd center is square planar.^[2]

References

↑ Shomir Ghosh, Xiang Wang, Anil Guram (2009). Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rd113.pub2.
↑ R. Kumar, A. W. Maverick, F. R. Fronczek, J. R. Doyle, N. C. Baenziger, M. A. M. Howells (1993). "The Pbca polymorph of dichloro(η⁴-1,5-cyclooctadiene)palladium(II)". Acta Crystallogr. C. 49: 1766–1767. doi:10.1107/S0108270193003889.

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Identifiers


CAS Number	12107-56-1^Y
3D model (JSmol)	Interactive image
ChemSpider	4642864
EC Number	235-161-8
PubChem CID	5702536
InChI InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; Key: RRHPTXZOMDSKRS-PHFPKPIQSA-L
SMILES C1CC=CCCC=C1.Cl[Pd]Cl
Properties
Chemical formula	C₈H₁₂Cl₂Pd
Molar mass	285.50 g·mol⁻¹
Appearance	yellow solid
Density	2.045 g/cm³
Melting point	210 °C (410 °F; 483 K)
Hazards
GHS pictograms
GHS signal word	Warning
GHS hazard statements	H315, H319, H335
GHS precautionary statements	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references