Shungite

Shungite is a black, lustrous, non-crystalline mineraloid consisting of more than 98 weight percent of carbon. It was first described from a deposit near Shunga village, in Karelia, Russia, from where it gets its name. Shungite has been reported to contain trace amounts of fullerenes (0.0001 < 0.001%).[1][2]

Shungite

Terminology

The term "shungite" was originally used in 1879 to describe a mineraloid with more than 98 percent carbon. More recently the term has also been used to describe shungite-bearing rocks, leading to some confusion.[3] Shungite-bearing rocks have also been classified purely on their carbon content, with shungite-1 having a carbon content in the range 98-100 weight percent and shungite-2, -3, -4 and -5 having contents in the ranges 35-80 percent, 20-35 percent, 10-20 percent and less than 10 percent, respectively.[3] In a further classification, shungite is subdivided into bright, semi-bright, semi-dull and dull on the basis of their luster (the terms lustrous and matte are also used for bright and dull).[4]

Shungite has two main modes of occurrence, disseminated within the host rock and as apparently mobilised material. Migrated shungite, which is bright (lustrous) shungite, has been interpreted to represent migrated hydrocarbons and is found as either layer shungite, layers or lenses near conformable with the host rock layering, or vein shungite, which is found as cross-cutting veins. Shungite may also occur as clasts within younger sedimentary rocks.[3]

Occurrence

Shungite has to date mainly been found in Russia. The main deposit is in the Lake Onega area of Karelia, at Zazhoginskoye, near Shunga, with another occurrence at Vozhmozero.[1] Two other much smaller occurrences have been reported in Russia, one in Kamchatka in volcanic rocks and the other formed by the burning of spoil from a coal mine at high temperature in Chelyabinsk.[5] Other occurrences have been described from Austria, India, Democratic Republic of Congo[1] and Kazakhstan.[6]

Formation

Shungite has been regarded as an example of abiogenic petroleum formation,[4] but its biological origin has now been confirmed.[3] Non-migrated shungite is found directly stratigraphically above deposits that were formed in a shallow water carbonate shelf to non-marine evaporitic environment. The shungite bearing sequence is thought to have been deposited during active rifting, consistent with the alkaline volcanic rocks that are found within the sequence. The organic-rich sediments were probably deposited in a brackish lagoonal setting. The concentration of carbon indicates elevated biological productivity levels, possibly due to high levels of nutrients available from interbedded volcanic material.[3]

The stratified shungite-bearing deposits that retain sedimentary structures are interpreted as metamorphosed oil source rocks. Some diapiric mushroom-shaped structures have been identified, which are interpreted as possible mud volcanoes. Layer and vein shungite varieties, and shungite filling vesicles and forming the matrix to breccias, are interpreted as migrated petroleum, now in the form of metamorphosed bitumen.[3]

Shunga deposit

The Shunga deposit contains an estimated total carbon reserve of more than 250 gigatonnes. It is found within a sequence of Palaeoproterozoic metasedimentary and metavolcanic rocks that are preserved in a synform. The sequence is dated by a gabbro intrusion, which gives a date of 1980±27 Ma, and the underlying dolomites, which give an age of 2090±70 Ma. There are nine shungite-bearing layers within the Zaonezhskaya Formation, from the middle of the preserved sequence. Of these the thickest is layer six, which is also known as the "Productive horizon", due to its concentration of shungite deposits. Four main deposits are known from the area, the Shungskoe, Maksovo, Zazhogino and Nigozero deposits. The Shungskoe deposit is the most studied and is mainly mined out.[3]

Uses

Shungite has been used as a folk medical treatment since the early 18th century. Peter the Great set up Russia's first spa in Karelia to make use of the water purifying properties of shungite, which he had himself experienced. He also instigated its use in providing purified water for the Russian army. The anti-bacterial properties of shungite have been confirmed by modern testing.[7]

Shungite has been used since the middle of the 18th century as a pigment for paint,[3] and is currently sold under the names "carbon black" or "shungite natural black".[5]

In the 1970s, shungite was exploited in the production of an insulating material, known as shungisite. Shungisite is prepared by heating rocks with low shungite concentrations to 1090–1130 °C and is used as a low density filler.[3]

References
  1. Mindat.org. "Shungite". Retrieved 3 July 2012.
  2. Reznikov, V.A.; PolekhovskiÏ (6 March 2000). "Technical Physics Letters, Vol. 26, No. 8, 2000, pp. 689–693. Translated from Pis'ma v Zhurnal TekhnicheskoÏ Fiziki, Vol. 26, No. 15, 2000, pp. 94–102" (PDF). Technical Physics Letters. 8. 26 (2000): 689–693. doi:10.1134/1.1307814. Retrieved 9 January 2013.
  3. Melezhik, V.A.; Filippov M.M.; Romashkin A.E. (2004). "A giant Palaeoproterozoic deposit of shungite in NW Russia: genesis and practical applications". Ore Geology Reviews. Elsevier. 24 (1–2): 135–154. doi:10.1016/j.oregeorev.2003.08.003.
  4. Mastarlez, M.; Glikson M.; Stankiewicz B.A.; Volkova I.B.; Bustin R.M. (2000). "Organic and mineral matter in a Precambrian shungite from Karelia, Russia". In Glikson M. & Mastarlez M. (ed.). Organic Matter and Mineralisation: Thermal Alteration, Hydrocarbon Generation, and Role in Metallogenesis. Springer. pp. 102–116. ISBN 9780412733307. Retrieved 7 July 2012.
  5. Easthaugh, N.; Walsh V.; Chaplin T.; Siddall R. (2008). Pigment Compendium: A Dictionary and Optical Microscopy of Historic Pigments. Routledge. p. 345. ISBN 9780750689809. Retrieved 2 July 2012.
  6. Efremova, S.V. (2006). "Water treatment with a shungite sorbent and biosorbents on its base". Russian Journal of Applied Chemistry. 79 (3): 397–402. doi:10.1134/s1070427206030128. Retrieved 7 July 2012.
  7. Volfson, I.F.; Farrakhov E.G.; Pronin A.P.; Beiseyev O.B.; Beiseyev A.O.; Bogdasarov M.A.; Oderova A.V.; Pechenkin I.G.; Khitrov A.E.; Pikhur O.L.; Plotkina J.V.; Frank-Kamanetskya O.V.; Rosseeva E.V.; Denisova O.A.; Chernogoryuk G.E.; Baranovskya N.; Rikhvanov L.P.; Petrov I.M.; Saghatelyan A.K.; Sahakyan L.V.; Menchinskaya O.V.; Zangiyeva T.D; Kajtukov M.Z.; Uzdenova Z.H.; Dorozhko A.L. (2011). "Medical Geology in Russia and NIS". In Selinus O.; Finkelman R.B.; Centeno J.A. (eds.). Medical Geology: A Regional Synthesis. Springer. p. 223. ISBN 9789048134298. Retrieved 7 July 2012.
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