Marrite

Marrite (mar'-ite) is depicted by the chemical formula PbAgAsS3. It is the arsenic equivalent of mineral freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite.[5] Marrite was named in honor of geologist John Edward Marr (1857–1933) of Cambridge, England.[4]

Marrite
The two arrows point to the marrite microcrystals (one or two at each arrow, dull), the rest is galena (bright)
General
CategorySulfosalt mineral
Formula
(repeating unit)
PbAgAsS3
Strunz classification2.JB.15
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/a
Unit cella = 7.29 Å, b = 12.68 Å,
c = 5.99 Å; β = 91.22°;
V = 553.57 Å3; Z = 4
Identification
Formula mass486.19 g/mol
ColorLead gray, steel gray
Crystal habitTabular or striated crystals
TwinningPartly bent twin lamellae observable in polished section.
CleavageNone
FractureConchoidal
TenacityBrittle
Mohs scale hardness3
LusterMetallic
StreakBlack with brownish tint
DiaphaneityOpaque
Specific gravity5.82
Optical propertiesBiaxial
Refractive indexAnistrophic
PleochroismWhite, with red internal reflections.
Other characteristicsOf hydrothermal origin along with other sulfosalts in dolomite.
References[1][2][3][4]

Crystal habit

Marrite is part of the monoclinic crystal class, and 2m point group.[3] The symmetry reveals that this mineral is composed of 3 axes of unequal lengths. Two of the axes are perpendicular at 90 degrees, while one axis intersects at an angle less than 90 degrees. Crystal habit includes striated, meaning it forms parallel lines along crystal faces; or tabular, meaning that structure dimensions are thin in 1 direction.[3]

Optical mineralogy

Under a microscope, marrite has a distinct anisotropic refractive index, meaning the velocity of light varies depending on the direction being traveled through the mineral. It is typical of anisotropic minerals to display colorful, optical properties when viewed under cross polarized light. This differs from its vague gray color when viewed in plane polarized light, which is the reason optical mineralogy is essential for correctly identifying similar minerals.[2] Marrite belongs to the biaxial optical class, which signifies that it has two optic axes. An optic axis is the direction of light that travels at 0 birefringence, causing the mineral to appear isotropic. When viewing the indicatrix of biaxial minerals, both optic axes are always perpendicular to one of the two circular sections.

Occurrence

The only known occurrence of Marrite is the type locality of the Lengenbach quarry in Binntal, Valais, Switzerland. It is primarily formed because of hydrothermal activity, which involves water and high temperatures. Marrite is predominately found in dolomite along with a variety of other sulfosalts.[4]

References

  1. Mineralienatlas
  2. "Marrite Mineral Information and Data." http://www.mindat.org/min-2579.html. Accessed 8 September 2010.
  3. Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1990) Marrite. Handbook of Mineralogy. 313 p. Mineral Data Publication. Tucson, Arizona.
  4. "Marrite Mineral Data." http://webmineral.com/data/Marrite.shtml. Accessed 8 September 2010.
  5. Berlepsch, P., Makovicky E., and Armbruster, T. (2002) Structural relationships between sicherite, marrite, freieslebenite, and diaphorite: Analysis based on anionic nets and polyhedral characteristics(178th edition) 75-91 p. E. Schweizerbart'sche Verlagsbuchhandlung. Stuttgart, Germany.
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