Lithium chloride (data page)

This page provides supplementary chemical data on Lithium chloride.

Solubility
Solubility of LiCl in various solvents
(g LiCl / 100g of solvent at 25 °C)
H2O84.5
Liquid ammonia3.02
Liquid sulfur dioxide0.012
Methanol21 - 41
Formic acid27.5
Sulfolane1.5
Acetonitrile0.14
Acetone0.83
Formamide28.2
Dimethylformamide11 - 28
Reference:
Burgess, J. Metal Ions in Solution
(Ellis Horwood, New York, 1978)
ISBN 0-85312-027-7

Thermodynamic properties
Phase behavior
Triple point ? K (? °C), ? Pa
Critical point ? K (? °C), ? Pa
Std enthalpy change
of fusionΔfusHo		 +19.9 kJ/mol
Std entropy change
of fusionΔfusSo		 ? J/(mol·K)
Std enthalpy change
of vaporizationΔvapHo		 ? kJ/mol
Std entropy change
of vaporizationΔvapSo		 ? J/(mol·K)
Solid properties
Std enthalpy change
of formation ΔfHosolid		 −408.27 kJ/mol
Standard molar entropy
Sosolid		 59.33 J/(mol K)
Heat capacity cp 47.99 J/(mol K)
Liquid properties
Std enthalpy change
of formation ΔfHoliquid		 −390.76 kJ/mol
Standard molar entropy
Soliquid		 ? J/(mol K)
Heat capacity cp ? J/(mol K)
Gas properties
Std enthalpy change
of formation ΔfHogas		 −195.2 kJ/mol
Standard molar entropy
Sogas		 212.7 J/(mol K)
Heat capacity cp 33.2 J/(mol K)

Spectral data
UV-Vis
Lambda-max ? nm
Extinction coefficient ?
IR
Major absorption bands ? cm−1
NMR
Proton NMR
Carbon-13 NMR
Other NMR data
MS
Masses of
main fragments

Structure and properties data
Structure and properties
Index of refraction 1.662
Dielectric constant ? C2/(N·m2) at ? °C
Bond strength ?
Bond length ?
Magnetic susceptibility -24.3 cgs units

Temperature Relative Humidity[1]
Temperature(C)Relative Humidity(%)
0.2314.7
9.5613.4
19.2212.4
29.6411.8
39.6411.8
46.7611.4

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

References
  1. Arnold, Wexler (1954). "Relative Humidity-Temperature Relationships of Some Saturated Salt Solutions in the Temperature Range 0 0 to 500 C". Journal of Research of the National Bureau of Standards. 53 (1): 19.
  • Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD), http://webbook.nist.gov

Except where noted otherwise, data relate to standard ambient temperature and pressure.

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