List of S-phrases

S-phrases are defined in Annex IV of European Union Directive 67/548/EEC: Safety advice concerning dangerous substances and preparations. The list was consolidated and republished in Directive 2001/59/EC, where translations into other EU languages may be found. The list was subsequently updated and republished in Directive 2006/102/EC, where translations to additional European languages were added.

These safety phrases are used internationally and not just in Europe, and there is an ongoing effort towards complete international harmonization. (Note: missing S-number combinations indicate phrases that were deleted or replaced by another phrase.)

CodePhrase
S1Keep locked up
S2Keep out of the reach of children
S3Keep in a cool place
S4Keep away from living quarters
S5Keep contents under ... (appropriate liquid to be specified by the manufacturer)
S6Keep under ... (inert gas to be specified by the manufacturer)
S7Keep container tightly closed
S8Keep container dry
S9Keep container in a well-ventilated place
S10Keep contents wet (No longer used)
S11Avoid contact with air (No longer used)
S12Do not keep the container sealed
S13Keep away from food, drink and animal foodstuffs
S14Keep away from ... (incompatible materials to be indicated by the manufacturer)
S15Keep away from heat
S16Keep away from sources of ignition - No smoking
S17Keep away from combustible material
S18Handle and open container with care
S20When using do not eat or drink
S21When using do not smoke
S22Do not breathe dust
S23Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
S24Avoid contact with skin
S25Avoid contact with eyes
S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27Take off immediately all contaminated clothing
S28After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S29Do not empty into drains
S30Never add water to this product
S33Take precautionary measures against static discharges
S35This material and its container must be disposed of in a safe way
S36Wear suitable protective clothing
S37Wear suitable gloves
S38In case of insufficient ventilation wear suitable respiratory equipment
S39Wear eye/face protection
S40To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
S41In case of fire and/or explosion do not breathe fumes
S42During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer)
S43In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46If swallowed, seek medical advice immediately and show this container or label
S47Keep at temperature not exceeding ... °C (to be specified by the manufacturer)
S48Keep wet with ... (appropriate material to be specified by the manufacturer)
S49Keep only in the original container
S50Do not mix with ... (to be specified by the manufacturer)
S51Use only in well-ventilated areas
S52Not recommended for interior use on large surface areas
S53Avoid exposure - obtain special instructions before use
S56Dispose of this material and its container at hazardous or special waste collection point
S57Use appropriate containment to avoid environmental contamination
S59Refer to manufacturer/supplier for information on recovery/recycling
S60This material and its container must be disposed of as hazardous waste
S61Avoid release to the environment. Refer to special instructions/safety data sheet
S62If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S63In case of accident by inhalation: remove casualty to fresh air and keep at rest
S64If swallowed, rinse mouth with water (only if the person is conscious)
S1/2Keep locked up and out of the reach of children
S3/7Keep container tightly closed in a cool place
S3/7/9Keep container tightly closed in a cool, well-ventilated place
S3/9/14Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
S3/9/14/49Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
S3/9/49Keep only in the original container in a cool, well-ventilated place
S3/14Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
S7/8Keep container tightly closed and dry
S7/9Keep container tightly closed and in a well-ventilated place
S7/47Keep container tightly closed and at temperature not exceeding ... °C (to be specified by the manufacturer)
S8/10Keep container wet, but keep the contents dry
S20/21When using do not eat, drink or smoke
S24/25Avoid contact with skin and eyes
S27/28After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer)
S29/35Do not empty into drains; dispose of this material and its container in a safe way
S29/56Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point
S36/37Wear suitable protective clothing and gloves
S36/37/39Wear suitable protective clothing, gloves and eye/face protection
S36/39Wear suitable protective clothing and eye/face protection
S37/39Wear suitable gloves and eye/face protection
S38/2In case of insufficient ventilation wear suitable respiratory equipment and stay away from children
S47/49Keep only in the original container at temperature not exceeding ... °C (to be specified by the manufacturer)

See also
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