Galena

Galena (lead glance)
	Galena close-up
General
Category	Sulfide mineral, octahedral subgroup
Formula; (repeating unit)	PbS
Strunz classification	2.CD.10
Dana classification	2.8.1.1
Crystal system	Cubic
Crystal class	Hexoctahedral (m3m) ; H–M symbol: (4/m 3 2/m)
Space group	Fm3m
Unit cell	a = 5.936 Å; Z = 4
Identification
Color	Lead gray and silvery
Crystal habit	Cubes and octahedra, blocky, tabular and sometimes skeletal crystals
Twinning	Contact, penetration and lamellar
Cleavage	Cubic perfect on [001], parting on [111]
Fracture	Subconchoidal
Tenacity	Brittle
Mohs scale hardness	2.5–2.75
Luster	Metallic on cleavage planes
Streak	Lead gray
Diaphaneity	Opaque
Specific gravity	7.2–7.6
Optical properties	Isotropic and opaque
Fusibility	2
Other characteristics	Natural semiconductor
References	[1][2][3]

Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.[4]

The rock-salt crystal structure. Each atom has six nearest neighbors, with octahedral geometry.

Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite.

Lead ore deposits

Galena with baryte and pyrite from Cerro de Pasco, Peru; 5.8 cm × 4.8 cm × 4.4 cm (2.3 in × 1.9 in × 1.7 in)

Cubic galena with calcite from Jasper County, Missouri, USA; 5.1 cm × 3.2 cm × 2.8 cm (2.0 in × 1.3 in × 1.1 in)

Galena is the main ore of lead, used since ancient times. Because of its somewhat low melting point, it was easy to liberate by smelting. It typically forms in low-temperature sedimentary deposits.

In some deposits the galena contains about 1–2% silver, a byproduct that far outweighs the main lead ore in revenue. In these deposits significant amounts of silver occur as included silver sulfide mineral phases or as limited silver in solid solution within the galena structure. These argentiferous galenas have long been an important ore of silver.

A microscopic picture of Galena

Galena deposits are found worldwide in various environments.[3] Noted deposits include those at Freiberg in Saxony;[1] Cornwall, the Mendips in Somerset, Derbyshire, and Cumberland in England; the Madan and Rhodope Mountains in Bulgaria; the Sullivan Mine of British Columbia; Broken Hill and Mount Isa in Australia; and the ancient mines of Sardinia. In the United States, it occurs most notably in the Mississippi Valley type deposits of the Lead Belt in southeastern Missouri,[1] and in the Driftless Area of Illinois, Iowa and Wisconsin.

Galena also was a major mineral of the zinc-lead mines of the tri-state district around Joplin in southwestern Missouri and the adjoining areas of Kansas and Oklahoma.[1] Galena is also an important ore mineral in the silver mining regions of Colorado, Idaho, Utah and Montana. Of the latter, the Coeur d'Alene district of northern Idaho was most prominent.[1]

The largest documented crystal of galena is composite cubo-octahedra from the Great Laxey Mine, Isle of Man, measuring 25 cm × 25 cm × 25 cm (10 in × 10 in × 10 in).[5]

Importance

Galena is the official state mineral of the U.S. states of Kansas, Missouri and Wisconsin; the former mining communities of Galena, Kansas, and Galena, Illinois, take their names from deposits of this mineral.

Crystal structure

Galena belongs to the octahedral sulfide group of minerals that have metal ions in octahedral positions, such as the iron sulfide pyrrhotite and the nickel arsenide niccolite. The galena group is named after its most common member, with other isometric members that include manganese bearing alabandite and niningerite.[3]

Divalent lead (Pb) cations and sulfur (S) anions form a close-packed cubic unit cell much like the mineral halite of the halide mineral group. Zinc, cadmium, iron, copper, antimony, arsenic, bismuth and selenium also occur in variable amounts in galena. Selenium substitutes for sulfur in the structure constituting a solid solution series. The lead telluride mineral altaite has the same crystal structure as galena.

Geochemistry

Within the weathering or oxidation zone galena alters to anglesite (lead sulfate) or cerussite (lead carbonate). Galena exposed to acid mine drainage can be oxidized to anglesite by naturally occurring bacteria and archaea, in a process similar to bioleaching.[6]

Galena uses

One of the oldest uses of galena was in the eye cosmetic kohl. In Ancient Egypt, this was applied around the eyes to reduce the glare of the desert sun and to repel flies, which were a potential source of disease.[7]

Galena was used as decoration in the prehistoric Mississippian city at Kincaid Mounds in present-day Illinois.[8]

Galena is the primary ore of lead, and is often mined for its silver content, such as at the Galena Mine in northern Idaho.

It can be used as a source of lead in ceramic glaze.[9]

Galena cat's whisker detector

Galena is a semiconductor with a small band gap of about 0.4 eV, which found use in early wireless communication systems. It was used as the crystal in crystal radio receivers, in which it was used as a point-contact diode capable of rectifying alternating current to detect the radio signals. The galena crystal was used with a sharp wire, known as a "cat's whisker" in contact with it.[10]

References

Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1990). "Galena". Handbook of Mineralogy (PDF). 1. Chantilly, VA: Mineralogical Society of America. ISBN 0962209708.
Galena. Webmineral
Galena. Mindat.org
Young, Courtney A.; Taylor, Patrick R.; Anderson, Corby G. (2008). Hydrometallurgy 2008: Proceedings of the Sixth International Symposium. SME. ISBN 9780873352666.
Rickwood, P. C. (1981). "The largest crystals" (PDF). American Mineralogist. 66: 885–907.
Da Silva, Gabriel (2004). "Kinetics and mechanism of the bacterial and ferric sulphate oxidation of galena". Hydrometallurgy. 75: 99. doi:10.1016/j.hydromet.2004.07.001.
Metropolitan Museum of Art (2005). The Art of Medicine in Ancient Egypt. New York. p. 10. ISBN 1-58839-170-1.
The Glittery Legacy of Lead at a Historic Native American Site, Atlas Obscura, November 7, 2019
Glaze, http://www.thepotteries.org/types/glaze.htm.
Lee, Thomas H. (2007). "The (Pre-)History of the Integrated Circuit: A Random Walk" (PDF). IEEE Solid-State Circuits Newsletter. 12 (2): 16–22. doi:10.1109/N-SSC.2007.4785573. ISSN 1098-4232.

External links

Case Studies in Environmental Medicine (CSEM): Lead Toxicity.
ToxFAQs: Lead.
Mineral Information Institute entry for lead.

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[HBM-1] Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1990). "Galena". Handbook of Mineralogy (PDF). 1. Chantilly, VA: Mineralogical Society of America. ISBN 0962209708.

[Webmineral-2] Galena. Webmineral

[Mindat-3] Galena. Mindat.org

[4] Young, Courtney A.; Taylor, Patrick R.; Anderson, Corby G. (2008). Hydrometallurgy 2008: Proceedings of the Sixth International Symposium. SME. ISBN 9780873352666.

[5] Rickwood, P. C. (1981). "The largest crystals" (PDF). American Mineralogist. 66: 885–907.

[6] Da Silva, Gabriel (2004). "Kinetics and mechanism of the bacterial and ferric sulphate oxidation of galena". Hydrometallurgy. 75: 99. doi:10.1016/j.hydromet.2004.07.001.

[7] Metropolitan Museum of Art (2005). The Art of Medicine in Ancient Egypt. New York. p. 10. ISBN 1-58839-170-1.

[8] The Glittery Legacy of Lead at a Historic Native American Site, Atlas Obscura, November 7, 2019

[9] Glaze, http://www.thepotteries.org/types/glaze.htm.

[Lee2007-10] Lee, Thomas H. (2007). "The (Pre-)History of the Integrated Circuit: A Random Walk" (PDF). IEEE Solid-State Circuits Newsletter. 12 (2): 16–22. doi:10.1109/N-SSC.2007.4785573. ISSN 1098-4232.