Flint

Neolithic flint axe, about 31 cm long

Flint was used in the manufacture of tools during the Stone Age as it splits into thin, sharp splinters called flakes or blades (depending on the shape) when struck by another hard object (such as a hammerstone made of another material). This process is referred to as knapping.[9]

Flint mining is attested since the Paleolithic, but became more common since the Neolithic (Michelsberg culture, Funnelbeaker culture). In Europe, some of the best toolmaking flint has come from Belgium (Obourg, flint mines of Spiennes),[10] the coastal chalks of the English Channel, the Paris Basin, Thy in Jutland (flint mine at Hov), the Sennonian deposits of Rügen, Grimes Graves in England, the Upper Cretaceous chalk formation of Dobruja and the lower Danube (Balkan flint), the Cenomanian chalky marl formation of the Moldavian Plateau (Miorcani flint) and the Jurassic deposits of the Kraków area and Krzemionki in Poland, as well as of the Lägern (silex) in the Jura Mountains of Switzerland.

In 1938, a project of the Ohio Historical Society, under the leadership of H. Holmes Ellis began to study the knapping methods and techniques of Native Americans. Like past studies, this work involved experimenting with actual knapping techniques by creation of stone tools through the use of techniques like direct freehand percussion, freehand pressure and pressure using a rest. Other scholars who have conducted similar experiments and studies include William Henry Holmes, Alonzo W. Pond, Francis H. S. Knowles and Don Crabtree.[11]

To combat fragmentation, flint/chert may be heat-treated, being slowly brought up to a temperature of 150 to 260 °C (300 to 500 °F) for 24 hours, then slowly cooled to room temperature. This makes the material more homogeneous and thus more knappable and produces tools with a cleaner, sharper cutting edge. Heat treating was known to stone age artisans.

A flint spark lighter in action

When struck against steel, a flint edge produces sparks. The hard flint edge shaves off a particle of the steel that exposes iron, which reacts with oxygen from the atmosphere and can ignite the proper tinder.[12]

Prior to the wide availability of steel, rocks of pyrite (FeS₂) would be used along with the flint, in a similar (but more time-consuming) way. These methods remain popular in woodcraft, bushcraft, and amongst people practising traditional fire-starting skills.[13][14]

Assorted reproduction firesteels typical of Roman to Medieval period

A later, major use of flint and steel was in the flintlock mechanism, used primarily in flintlock firearms, but also used on dedicated fire-starting tools. A piece of flint held in the jaws of a spring-loaded hammer, when released by a trigger, strikes a hinged piece of steel ("frizzen") at an angle, creating a shower of sparks and exposing a charge of priming powder. The sparks ignite the priming powder and that flame, in turn, ignites the main charge, propelling the ball, bullet, or shot through the barrel. While the military use of the flintlock declined after the adoption of the percussion cap from the 1840s onward, flintlock rifles and shotguns remain in use amongst recreational shooters.

Flint and steel used to strike sparks were superseded by ferrocerium (sometimes referred to as "flint", although not true flint, "mischmetal", "hot spark", "metal match", or "fire steel"). This man-made material, when scraped with any hard, sharp edge, produces sparks that are much hotter than obtained with natural flint and steel, allowing use of a wider range of tinders. Because it can produce sparks when wet and can start fires when used correctly, ferrocerium is commonly included in survival kits. Ferrocerium is used in many cigarette lighters, where it is referred to as "a flint".

Flint's utility as a fire starter is hampered by its property of uneven expansion under heating, causing it to fracture, sometimes violently, during heating. This tendency is enhanced by the impurities found in most samples of flint that may expand to a greater or lesser degree than the surrounding stone, and is similar to the tendency of glass to shatter when exposed to heat, and can become a drawback when flint is used as a building material.[15]

Flint, knapped or unknapped, has been used from antiquity (for example at the Late Roman fort of Burgh Castle in Norfolk) up to the present day as a material for building stone walls, using lime mortar, and often combined with other available stone or brick rubble. It was most common in those parts of southern England where no good building stone was available locally, and where brick-making not widespread until the later Middle Ages. It is especially associated with East Anglia, but also used in chalky areas stretching through Hampshire, Sussex, Surrey and Kent to Somerset.

Flint was used in the construction of many churches, houses, and other buildings, for example, the large stronghold of Framlingham Castle. Many different decorative effects have been achieved by using different types of knapping or arrangement and combinations with stone (flushwork), especially in the 15th and early 16th centuries. Because knapping flints to a relatively flush surface and size is a highly skilled process with a high level of wastage, flint finishes typically indicate high status buildings.

• 
  A flint church – the Parish Church of Saint Thomas, in Cricket Saint Thomas, Somerset, England. The height of the very neatly knapped flints varies between 3 and 5 inches (7.6 and 12.7 cm).
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  Close-up of the wall of the Roman shore fort at Burgh Castle, Norfolk, showing alternating courses of flint and brick
• 
  A typical medieval wall (with modern memorial) at Canterbury Cathedral – knapped and unknapped ("cobble") flints are mixed with pieces of brick and other stones
• 
  Ruins of Thetford Priory show flints and mortar through the whole depth of the wall

Flint pebbles are used as the media in ball mills to grind glazes and other raw materials for the ceramics industry.[16] The pebbles are hand-selected based on colour; those having a tint of red, indicating high iron content, are discarded. The remaining blue-grey stones have a low content of chromophoric oxides and so are less deleterious to the colour of the ceramic composition after firing.[17]

Until recently flint was also an important raw material in clay-based ceramic bodies produced in the UK.[18][19] In preparation for use flint pebbles, frequently sourced from the coasts of South-East England or Western France, were calcined to around 1,000 °C (1,800 °F). This heating process both removed organic impurities and induced certain physical reactions, including converting some of the silica to cristobalite. After calcination the flint pebbles were milled to a fine particle size.[20][21][22][23] However, the use of flint has now been superseded by quartz.[24] Because of the historical use of flint, the word "flint" is used by some potters, especially in the US, to refer to siliceous materials that are not flint.[25][26][27]

Flint bracelets were known in Ancient Egypt, and several examples have been found.[28]