Bathocuproine
Bathocuproine is a derivative of 1,10-phenanthroline with two methyl groups and two phenyl groups in the 2,9 and 4,7 positions, respectively. Like 1,10-phenanthroline, bathocuproine is a bidentate chelating ligand. The two methyl groups flank the nitrogen centers, such that bathocuproine is a bulky ligand. It is a pale yellow solid that is soluble in polar organic solvents.[1]
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Other names
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, 2,9-Dimethyl-4,7-diaphenyl-1,10-phenanthroline
2,9-Dimethyl-4,7-diphenylphenanthroline, 4,7-Diphenyl-2,9-dimethyl-1,10-phenanthroline, BCP | |
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ChemSpider | |
ECHA InfoCard | 100.022.945 |
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Properties | |
C26H20N2 | |
Molar mass | 360.460 g·mol−1 |
Appearance | Pale yellow solid |
Melting point | 283 °C (541 °F; 556 K) |
organic solvents | |
Hazards | |
GHS pictograms | |
GHS Signal word | Warning |
GHS hazard statements |
H302, H413 |
P264, P270, P273, P301+312, P330, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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References
- Guosheng Liu, Yichen, Wu (2012). "Bathocuproine". Encyclopedia of Reagents for Organic Synthesis. eEROS. doi:10.1002/047084289X.rn01392. ISBN 978-0471936237.CS1 maint: multiple names: authors list (link)
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