Julius Lothar Meyer

Julius Lothar Meyer
Meyer in 1883
Born 19 August 1830
Varel, Germany
Died 11 April 1895 (aged 65)
Tübingen
Nationality German
Alma mater University of Würzburg, University of Breslau
Known for Periodic table of chemical elements
Awards Davy Medal (1882)
Scientific career
Fields Chemistry
Institutions University of Tübingen
Influences Robert Bunsen

Julius Lothar Meyer (19 August 1830 – 11 April 1895) was a German chemist. He was one of the pioneers in developing the first periodic table of chemical elements. Both Mendeleev and Meyer worked with Robert Bunsen. He never used his first given name, and was known throughout his life simply as Lothar Meyer.

Career

Lothar Meyer was born in Varel, Germany (then part of the Duchy of Oldenburg). He was the son of Friedrich August Meyer, a physician, and Anna Biermann. After attending the Altes Gymnasium in Oldenburg, he studied medicine at the University of Zurich in 1851. Two years later, he studied at the University of Würzburg, where he studied pathology, as a student of Rudolf Virchow. At Zurich, he had studied under Carl Ludwig, which had prompted him to devote his attention to physiological chemistry. After graduating as a Doctor of Medicine from Würzburg in 1854, he went to University of Heidelberg, where Robert Bunsen held the chair of chemistry. In 1858, he received a Doctor of Chemistry from University of Breslau with a thesis on the effects of carbon monoxide on the blood. With this interest in the physiology of respiration, he had recognized that oxygen combines with the hemoglobin in blood.[1][2]

Influenced by the mathematical teaching of Gustav Kirchhoff, he took up the study of mathematical physics at Königsberg under Franz Ernst Neumann, and in 1859, after having received his habilitation, he became Privatdozent in physics and chemistry at the University of Breslau. In 1866, Meyer accepted a post at the Eberswalde Forestry Academy at Neustadt-Eberswalde but two years later was appointed to a professorship at the Karlsruhe Polytechnic.[3]

In 1872, Meyer was the first to suggest that the six carbon atoms in the benzene ring (that had been proposed a few years earlier by August Kekulé) were interconnected by single bonds only, the fourth valence of each carbon atom being directed toward the interior of the ring.

During the Franco-German campaign, the Polytechnic was used as a hospital, and Meyer took an active role in the care of the wounded. In 1876, Meyer became Professor of Chemistry at the University of Tübingen, where he served until his death.[3]

Periodic table

Meyer is best known for his part in the periodic classification of the elements. He noted, as J. A. R. Newlands did in England, if each element is arranged in the order of their atomic weights, they fall into groups of similar chemical and physical properties repeated at periodic intervals. According to him, if the atomic weights were plotted as ordinates and the atomic volumes as abscissae—the curve obtained a series of maxima and minima—the most electro-positive elements appearing at the peaks of the curve in the order of their atomic weights.[3]

His book, Die modernen Theorien der Chemie, which he began writing in Breslau in 1862 and which was published two years later (The Internet Database of Periodic Tables. Hemogenesis web book), contained an early version of the periodic table containing 28 elements, classified elements into six families by their valence—for the first time, elements had been grouped according to their valence. Works on organizing the elements by atomic weight, until then had been stymied by inaccurate measurements of the atomic weights.

He published articles about classification table of the elements in horizontal form (1862, 1864) and vertical form (1870), in which the series of periods are properly ended by an element of the earth metal group.[4]

In 1869, Dmitri Mendeleev published a periodic table of all known elements (he predicted several new elements to complete the table, and corrected some atomic weights). A few months later, Meyer published a revised and expanded version of his 1864 table independently, which was similar to that published by Mendeleev (Meyer had been sent a copy of Mendeleev's table earlier; Mendeleev had sent it to many well-known chemists of his day) and a paper showing graphically the periodicity of the elements as a function of atomic weight. Meyer, as well as other chemists, was doubtful about Mendeleev's periodic law, and he criticized Mendeleev for "changing existing elements' atomic weights, only regarding possibility of periodical law in its structure". However, Mendeleev's work received significant support, when the new elements were found as predicted and atomic weights accordingly.

In 1882, both Meyer and Mendeleev received the Davy Medal from the Royal Society in recognition of their work on the Periodic Law.

The newly discovered mineral lotharmeyerite, Ca(Zn,Mn3+)2(AsO4)2•2(H2O,OH), was named in recognition of Meyer's work on the Periodic Law in 1983. The type locality is the Ojuela mine, Mapimí, Durango, Mexico.[5] Four closely related minerals have been described since 1983: ferrilotharmeyerite, Ca(Fe3+,Zn)2(AsO4)2•2(OH,H2O) (1992);[6] cobaltlotharmeyerite, Ca(Co,Fe3+,Ni)2(AsO4)2•2(H2O,OH) (1997)[7]; nickellotharmeyerite, Ca(Ni,Fe3+,Co)2(AsO4)2•2(H2O,OH) (1999)[8]; and manganlotharmeyerite, CaMn3+2(AsO4)2(OH)2 (2002).[9]

Meyer's table with vertical display of periods in 1870

IIIIIIIVVVIVIIVIIIIX
BAlIn(?)Tl
CSi
Ti

Zr
SnPb
NP
V
As
Nb
Sb
Ta
Bi
OS
Cr
Se
Mo
Те
W
F




Cl





Mn
Fe
Co
Ni
Br





Ru
Rh
Pd
I





Os
Ir
Pt
LiNaK
Cu
Rb
Ag
Cs
Au
BeMgCa
Zn
Sr
Cd
Ba
Hg

Personal life

Meyer married Johanna Volkmann in 1866.[10]

See also

Notes

  1. Sergei Vinogradskii and the Cycle of Life: From the Thermodynamics of Life ..., Lloyd Ackert
  2. The Disappearing Spoon...and other true tales from the Periodic Table, Sam Kean
  3. 1 2 3  This article incorporates text from a publication now in the public domain: Chisholm, Hugh, ed. (1911). "Meyer, Julius Lothar". Encyclopædia Britannica. 18 (11th ed.). Cambridge University Press. pp. 348–349.
  4. Makeyev A.K. (2013). "Julius Lothar Meyer was first to build the periodic table of elements". European applied sciences. 4 (2): 49–61. Archived from the original on 15 July 2013.
  5. Lotharmeyerite. https://www.mindat.org/min-2439.html, accessed 6/15/2018.
  6. Ferrilotharmeyerite. https://www.mindat.org/min-1495.html, accessed 6/15/2018.
  7. Cobaltlotharmeyerite. https://www.mindat.org/min-6885.html, accessed 6/15/2018.
  8. Nickellotharmeyerite. https://www.mindat.org/min-11004.html, accessed 6/15/2018.
  9. Manganlotharmeyerite. https://www.mindat.org/min-11206.html, accessed 6/15/2018.
  10. Krätz, Otto (1994), "Meyer, Lothar", Neue Deutsche Biographie (NDB) (in German), 17, Berlin: Duncker & Humblot, pp. 304–306 ; (full text online)

References

  • Wikisource Chisholm, Hugh, ed. (1911). "Meyer, Julius Lothar". Encyclopædia Britannica (11th ed.). Cambridge University Press.
  • Seubert, Karl (1918). "Nekrolog: Lothar Meyer". Berichte der deutschen chemischen Gesellschaft. 28 (4): 1109–1146. doi:10.1002/cber.18950280498.
  • Harald Kluge and Ingrid Kaestner, Ein Wegbereiter der physikalischen Chemie im 19. Jahrhundert, Julius Lothar Meyer (1830–1895) (Aachen: Shaker-Verlag, 2014).
  • Otto Kraetz, "Lothar Meyer," Neue Deutsche Biographie, 17 (1994), 304–6.
  • Works by or about Julius Lothar Meyer at Internet Archive
  • Periodic table according to Lothar Meyer (1870)
  • Video of a talk by Michael Gordin titled "Periodicity, Priority, Pedagogy: Mendeleev and Lothar Meyer"
  • The Internet Database of Periodic Tables. Chemogenesis web book.
  •  "Meyer, Lothar Julius". Encyclopedia Americana. 1920.
  • Eric Scerri's website on the periodic table
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