Azepane

Azepane
Skeletal formula of azepane
Ball-and-stick model of the azepane molecule
Names
IUPAC name
Azepane
Other names
  • Hexahydroazepine
  • Hexamethyleneimine
  • Homopiperidine
  • Perhydroazepine
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.003.524
Properties
C6H13N
Molar mass 99.18 g·mol−1
Density 0.88 g/cm3[1]
Boiling point 138 °C (280 °F; 411 K)[1] (749 mmHg)
Hazards
Flash point 18 °C (64 °F; 291 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Azepane is a saturated heterocycle, containing one nitrogen atom in seven-membered ring.

Analogous to the well-known reaction of other amines,[2][3] azepane reacts with CO2 and in principle can be used for carbon capture.[4]

Azepane-containing drugs

Molinate is a commercial pesticide that is derived from azepane.
  1. Amicibone
  2. Bacmecillinam (KW 1100)
  3. Beperidium
  4. Brazergoline
  5. Buzepide (Fenpipramide homolog).
  6. Cetiedil
  7. Gimantan
  8. Glidazamide
  9. Glisoxepide
  10. Glypinamide
  11. Hexacaine
  12. Mecillinam
  13. Molinate
  14. MR-16728 (cetiedil analogue)
  15. Nabazenil
  16. Pincainide
  17. Prozapine
  18. Setastine
  19. Tolazamide
  20. Pubchem 11142404

See also

References

  1. 1 2 "Hexamethyleneimine".
  2. ↑ Caplow, M. (1968). "Kinetics of Carbamate Formation and Breakdown". J. Am. Chem. Soc. 90 (24): 6795–6803. doi:10.1021/ja01026a041.
  3. ↑ Danckwerts, P. V. (1979). "The Reaction of CO2 with Ethanolamines". Chem. Eng. Sci. 34 (4): 443–446. doi:10.1016/0009-2509(79)85087-3.
  4. ↑ Sanz-Pérez, E. S.; Arencibia, A.; Sanz, R.; Calleja, G. (2016). "New developments on carbon dioxide capture using amine-impregnated silicas". Adsorption. 22 (4): 366–375. doi:10.1007/s10450-015-9740-2.
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